Type A: synthesized at room temperature and ambient atmosphere
Type B: Solvothermal synthesis
2. Characterizations
Form:
Powder crystal
A two-dimensional planar material with one-dimensional channels
Solubility:
Insoluble in water or common organic solvents (N,N-dimethylformamide, tetrahydrofuran, dimethyl sulfoxide, acetone, trichloromethane)
Stability (Tg):
~310 oC
BET Surface Area:
Type A: 200-300 m2/g
Type B: ~500 m2/g
Pore Size:
1.2 nm
Typical SEM Image of COF-LZU1
FT-IR spectra of COF-LZU1 (red), 1,3,5-triformylbenzene 1 (blue), and 1,4-diaminobenzene 2 (black).
Observed (black) and refined (red) PXRD profiles of COF-LZU1 with an eclipsed arrangement, background profile (blue) and difference plot (purple, observed minus refined).
The architecture of COF-LZU1 with a staggered arrangement. (For clarity, C blue and N red are shown only on the top layer, and H atoms are totally omitted.)
N2 adsorption (filled symbols) and desorption (empty symbols) isotherms of COF-LZU1 (cycles)-Type B
Langmuir surface area plot for ACS Material COF-LZU1 calculated from the isotherm-Type B
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